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Abstract Mid‐ocean ridges generate basalt and harzburgite, which are introduced into the mantle through subduction as a mechanical mixture, contributing to both lateral and radial compositional heterogeneity. The possible accumulation of basalt in the mantle transition zone has been examined, but details of the mantle composition below the 660‐km discontinuity (hereafter d660) remain poorly constrained. In this study, we utilize the subtle waveform details ofS660S, the underside shear‐wave reflection off the d660, to interpret the seismic velocity, density, and compositional structure near, and particularly below, the d660. We identify a significant difference inS660Swaveform shape in subduction zones compared to other regions. The inversion results reveal globally enriched basalt at the d660, with a notably higher content in subduction zones, consistent with the smaller impedance jump andS660Speak amplitude. The basalt fraction decreases significantly to less than 10% near 800‐km depth, forming a global harzburgite‐enriched layer and resulting in a steep seismic velocity gradient just below the d660, in agreement with 1D global reference models. The striking compositional radial variations near the d660 verify geodynamic predictions and challenge the applicability of homogeneous radial compositional models in the mantle. These variations may also affect the viscosity profile and, consequently, the dynamics at the boundary between the upper and lower mantle. 

Abstract Alaska is a tectonically active region with a long history of subduction and terrane accretion, but knowledge of its deep seismic structure is limited by a relatively sparse station distribution. By combining data from the EarthScope Transportable Array and other regional seismic networks, we obtain a high‐resolution state‐wide map of the Moho and upper‐mantle discontinuities beneath Alaska using teleseismic SH‐wave reverberations. Crustal thickness is generally correlated with elevation and the deepest Moho is in the region with basal accretion of the subducted Yakutat plate, consistent with its higher density due to a more mafic composition. The crustal thickness in the Brooks Range agrees with the prediction based on Airy isostasy and the weak free‐air gravity anomaly, suggesting that this region probably does not have significant density anomalies. We also resolve the 410, 520, and 660 discontinuities in most regions, with a thickened mantle transition zone (MTZ) and a normal depth difference between the 520 and 660 discontinuities (d660‐d520) under central Alaska, indicating the presence of the subducted Pacific slab in the upper MTZ. A near‐normal MTZ and a significantly smaller d660‐d520 are resolved under southeastern Alaska, suggesting potential mantle upwelling in the lower MTZ. Beneath the Alaska Peninsula, the thinned MTZ implies that the Pacific slab may not have reached the MTZ in this region, which is also consistent with recent tomography models. Overall, the results demonstrate a bent or segmented Pacific slab with varying depths under central Alaska and the Alaska Peninsula.